The 2154 raid in which Orion interceptors abducted nine members of the Enterprise NX-01 crew, including T'Pol, to sell them at a slave market in the Borderland.
The abduction occurs in the Enterprise episode Borderland. Enterprise enters the lawless region between the Orion Syndicate and the Klingon Empire in pursuit of the Augments, with the imprisoned geneticist Arik Soong aboard as a guide. Two Orion interceptors attack and beam away nine of the crew.
Soong leads Archer to an Orion processing station where captives are fitted with neurolytic restraints and auctioned. T'Pol is among those put up for sale. Archer lets himself be taken to reach his people.
Soong, who knows the system from his own past, shuts down the restraints, and the captives riot while Enterprise beams its people out. Soong uses the confusion to try to escape. The episode is the first of three covering the Augment crisis.